Polymer molecular weight distribution and definitions of. Polymer chemistry outline week 2 polymer formation step growth polymer formation chain. Chemistry 5861 polymer chemistry 2 a b c 3 a b c molecular weights typically from a few dozen to a few thousand each molecule in a pure sample is identical except for isotopomers sample structure independent of preparation route extended solids a very large network. The genesis of polymer theory is the realization that a conformation of a polymer chain can be modeled as the figure 3. Taylor macrocycle synthesis edited by david parker highpressure techniques in chemistry and physics edited by wilfried b. Pdf principles of polymerization 4th ed by odian minh kim. Principles of polymerization by george odian alibris.
Supplementary handouts will be used frequently and will be handed out in lecture as needed during the course. The process by which the polymers are formed is called polymerisation. Inorganic polymer chemistry pdf 30p this note covers the following topics. A polymer is a high molecular mass compound ranging from 5000 to one million and they are formed by the combination of a large number of one or more low molecular weight compounds. Can anyone recommend a good introductory polymer book. Odian or introduction to polymers, third edition by young and lovell more academic in style. Polydispersity index mw mn the larger the polydispersity index, the broader the molecular weight. Meeting the analytical challenges of modern polymer chemistry. They are a main constituent of our food starch, protein, etc. It is eminently useful for teaching polymer science in departments of chemistry, chemical engineering, and material science, and also for teaching polymer science and technology in polymer science institutes, which concentrate entirely on the science and technologies of polymers. Paul heimenz polymer chemistry and colloid science odian principles of polymerization malcom stevens polymer chemistry an introduction this is a pretty good introductory synthetic book. Odian polysilicones, aerogel wiki, aerogel movie yellow and blue are due to 1l6 rayleigh. The book is a very comprehensive collection of the polymerization principles that you should be aware of as a beginner grad student. Describes the physical and organic chemistry of the reactions by which polymer molecules are synthesized.
Chemical engineering 160260 polymer science and engineering. The polymers can exhibit stereo specificity if the. Apart from increased sophistication in methods of measuring molecular weight, such as the cryoscopic and vapour pressure methods, almost the whole range of the spectrum has been called into service to elucidate polymer structure. The following books are on reserve at the kenan chemistry library.
The emergence of new and increasingly complex synthetic biopolymers, novel polymers, and polymer additives with a broad range of structural and compositional diversity has been a driving force in the development of advanced separation and analytical technologies for polymer characterization. Structure of polyacenaphthylene obtained in the system liquid sulfur. The coordination polymerization is invented by two italian scientists. Introduction to materials science, chapter 15, polymers. The best controlled synthetic polymers narrow polymers used for calibrations have mwmn of 1. A wide variety of unsaturated monomers may be used, to yield polymers with. Industrial polymer chemistry focuses on the enduse application of products, with a smaller emphasis on applied research and preparation. Yet the practical applications of polymers are only increasing. Rubinsteins textbook is another great introduction to polymer physics especially scaling principles, percolation, and fractal behavior, and hiemenez and lodges book is a good resource for. Principles of polymerization 4th edition by odian solution. Free polymer chemistry books download ebooks online. Principles of polymerization george odian solutions manual. Polymer chemistry polymer american chemical society.
If you want a general polymer chemistry book to go along with saunders then id recommend principles of polymerization, 4th edition by g. They shared the nobel prize in chemistry in 1963 using zieglernatta catalysts to polymerize nonpolar monomers. Isaacs preparation of alkenes edited by jonathan m. All general polymer science books published after this were copies of this book. Used for styrene, methyl methacrylate, vinyl chloride, vinyl acetate. Glass transition temperature tg polymer chemistry anna university engineering chemistry1 notes cy6151 unit1 polymer chemistry properties of polymer glass transition. Polymer is a high molecular mass molecule formed by linking up of two or more small. These weak binding forces permit the polymer to be stretched. Iupac classification document for polymers pdf file.
Begins by introducing the characteristics which distinguish polymers from their much smaller sized homologs. Chemical engineering 160260 polymer science and engineering lecture. The unit substance or substances from which the polymer is obtained is called a monomer. Twoelectron transposition initiation reactions 85 3. Find materials for this course in the pages linked along the left. Introduction to materials science, chapter 15, polymer structures. A monodisperse polymer where all the chain lengths are equal such as a protein has an mwmn 1. Odian, principles of polymerization, mcgrawhill book co. This course assumes knowledge of organic chemistry 5.
These notes are preliminary and may contain errors. Note that all acyclic subunits except ch2 and ch2 ch2 are named as. Dhara,department of chemistry and biochemistry,iit kharagpur. Chemistry notes for class 12 chapter 15 polymers the word polymer has a greek origin. A read is counted each time someone views a publication summary such as the title, abstract, and list of authors, clicks on a figure, or views or downloads the fulltext. Polymer chemistry, sixth edition nanjing university.
A large molecule macromolecule built up by repetitive bonding covalent of smaller molecules monomers generally not a well defined structure, or molecular weight. Syllabus problem sets quizzes and exams old exams about dr. Good web page for polyurethane,urea, and polymer chemistry in general mst. The series lecture notes in chemistry lnc reports new developments in chemistry and. Fundamentals of polymer chemistry scientific spectator. Syllabus synthesis of polymers chemical engineering. Proceeds to a detailed study of three types of polymerization reactions. Odian polysilicones, aerogel wiki, aerogel movie yellow and blue are due to 1 l6 rayleigh. Uc materials engineering polymerplastics course sequence for undergraduates. Further, the focus is more towards the organic chemistry aspects and less towards the physical chemistry aspects.
Illustration of a complete registry and b entropic frustration for a chain bearing both positive and negative charges. High polymer is formed immediately in a chain reaction. Polymer is defined as a chemical substance of a high molecular mass formed by the combination of a large number of simple molecules, called monomers. Book principles of polymerization odian solution manual. The practical approach in chemistry series organocopper reagents edited by richard j. Notes on terminology for molar masses in polymer science. Principles of polymerization fourth edition george odian college of staten. Fundamentals of polymer chemistry pdf 48p download book. Schematic of a random coil polymer, and the density distribution fr for b, r, rg. Mod01 lec01 introduction to polymers polymer chemistry by dr. At the doubly bonded carbons the vinyl groups and is called vinyl polymerization. Pages can include considerable notesin pen or highlighterbut the notes cannot obscure the text.
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